It ranges from the £24,750 2.4D S to the £34,495 T6 SE Lux.
Dealers will get their demonstrators in October. Volvo said more than 250 customer orders have already been placed.
Starting at £24,7501, the Volvo XC60 will be available in three trim levels: S, SE and SE Lux and will have the choice of three engines: the turbocharged T6 producing 285bhp, and two variants of the D5 turbodiesel generating 185bhp and 163bhp.
The S variant's specification includes 17" alloy wheels, front fog lights, roof rails and rear spoiler, as well as advanced safety systems including City Safety and RSC (Roll Stability Control).
Interior details include electronic climate control, information centre, cruise control, leather steering wheel with remote audio controls, aluminium trim and performance sound audio system with aux input and CD player.
SE trim adds hill descent control, power driver’s seat with memory and autofolding power door mirrors with ground lights, Eriksberg T-Tec/Textile upholstery, autodimming rear view mirror with compass and chrome window trim.
SE Lux gains luxury features such as chronographic instrument dials, leather upholstery, natural wood trim, powered heated front seats, chrome detailing, 18" alloy wheels, active bending headlamps, power tailgate and rear park assist.